Back to Search
Start Over
N‐(sulfonio)sulfilimin‐Reagenzien: Nicht‐oxidierende Quellen von elektrophilen Stickstoffatomen für Skeletal Editing.
- Source :
-
Angewandte Chemie . 6/17/2024, Vol. 136 Issue 25, p1-7. 7p. - Publication Year :
- 2024
-
Abstract
- This article discusses the synthesis and reactivity of a new sulfonium salt that can transfer a sulfonitrene unit to C=C double bonds. The salt was synthesized on a large scale and is stable in air and water. It was used in two different transformations, expanding indenes to isoquinolines and contracting arylcyclobutenes to cyanocyclopropanes. The reagent is versatile and can tolerate various functional groups, making it a useful tool in skeletal editing. The authors acknowledge funding and provide supporting information for further details. [Extracted from the article]
Details
- Language :
- English
- ISSN :
- 00448249
- Volume :
- 136
- Issue :
- 25
- Database :
- Academic Search Index
- Journal :
- Angewandte Chemie
- Publication Type :
- Academic Journal
- Accession number :
- 177773199
- Full Text :
- https://doi.org/10.1002/ange.202403826