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Investigation of microstructure evolution and redox behavior of Ni-GDC cermet by cyclic re-oxidation in CO2.
- Source :
-
International Journal of Hydrogen Energy . Jun2024, Vol. 72, p958-966. 9p. - Publication Year :
- 2024
-
Abstract
- The microstructure and reactivity of Ni-GDC cermet under cyclic oxidation in CO 2 conditions were investigated using temperature-programmed reduction (TPR), X-ray diffraction (XRD), and scanning electron microscopy (SEM). The XRD results revealed that NiO was formed during the re-oxidation process in CO 2. SEM and TPR results demonstrated that nanostructured NiO aggregates were formed on the surface of the sample after being re-oxidized at 400 °C for 1200 min, resulting in an α peak with high reduction activity and a conversion of only 16% from Ni to NiO. In contrast, the samples re-oxidized at 600 °C for 600 min and 800 °C for 240 min were completely oxidized, resulting in reconstructed and sintered NiO with larger particle size, and a β peak with lower reactivity and a conversion of 100%. Redox cycling was further conducted on completely oxidized samples, which showed a decrease in β peak temperature from the first to seventh cycle. The migration and redistribution of sintered NiO towards the exterior were confirmed by comparing SEM images after the first and fourth cycles, which favored an increase in the reactive area. Therefore, this study reveals that lower re-oxidation temperatures (≤400 °C) and an appropriate increase in redox cycles are beneficial for forming surficial nanostructures while hindering the formation of large sintered NiO particles. [Display omitted] • Low oxidation temp range favors surface nanoparticles for NiO-GDC in CO 2. • High re-oxidation temp ranges can promote the migration and growth of NiO. • Long re-oxidation time in CO 2 can cause the bulk reconstruction and sintering. • Redox cycle favors sintered large NiO re-dispersive to improve reduction activity. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 03603199
- Volume :
- 72
- Database :
- Academic Search Index
- Journal :
- International Journal of Hydrogen Energy
- Publication Type :
- Academic Journal
- Accession number :
- 177909064
- Full Text :
- https://doi.org/10.1016/j.ijhydene.2024.05.478