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Proton-assisted activation of a MnIII–OOH for aromatic C–H hydroxylation through a putative [MnV=O] species.
- Source :
-
Chemical Communications . 6/28/2024, Vol. 60 Issue 51, p6520-6523. 4p. - Publication Year :
- 2024
-
Abstract
- Adding HClO4 to [(BnTPEN)MnIII–OO]+ in MeOH generates a short-lived MnIII–OOH species, which converts to a putative MnV=O species. The potent MnV=O species in MeCN oxidizes the pendant phenyl ring of the ligand in an intramolecular fashion. The addition of benzene causes the formation of (BnTPEN)MnIII-phenolate. These findings suggest that high valent Mn species have the potential to catalyze challenging aromatic hydroxylation reactions. [ABSTRACT FROM AUTHOR]
- Subjects :
- *HYDROXYLATION
*SPECIES
*BENZENE
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 60
- Issue :
- 51
- Database :
- Academic Search Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 178005904
- Full Text :
- https://doi.org/10.1039/d4cc00798k