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Rhodium perfluorobutyramide (Rh2(pfm)4): a synthetically useful catalyst for olefin aziridinations

Authors :
Keaney, Gregg F.
Wood, John L.
Source :
Tetrahedron Letters: International Organ for the Rapid Publication of Preliminary Communications in Organic Chemistry. Jun2005, Vol. 46 Issue 23, p4031-4034. 4p.
Publication Year :
2005

Abstract

Abstract: Rhodium perfluorobutyramide (Rh2(pfm)4) has been shown to catalyze the conversion of olefins to trichloroethoxysulfonyl, nosyl, and tosyl aziridines. Advantages of this aziridination procedure include the microwave-assisted preparation of the catalyst and the practical use of the alkene substrate as the limiting reagent. [Copyright &y& Elsevier]

Details

Language :
English
ISSN :
00404039
Volume :
46
Issue :
23
Database :
Academic Search Index
Journal :
Tetrahedron Letters: International Organ for the Rapid Publication of Preliminary Communications in Organic Chemistry
Publication Type :
Academic Journal
Accession number :
17822807
Full Text :
https://doi.org/10.1016/j.tetlet.2005.04.027