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Porous organic crystals crosslinked by free-radical reactions.
- Source :
-
Chemical Communications . 7/21/2024, Vol. 60 Issue 57, p7311-7314. 4p. - Publication Year :
- 2024
-
Abstract
- Two hydrogen-bonded crosslinked organic frameworks (HCOFs) were synthesized via free radical reactions utilizing butadiene and isoprene as crosslinkers. These HCOFs exhibit high crystallinity, enabling detailed structural characterization via single-crystal X-ray diffraction analysis. Subsequently, one of the olefin-rich HCOFs was converted to a hydroxylated framework through hydroboration–oxidation while maintaining the high crystallinity. [ABSTRACT FROM AUTHOR]
- Subjects :
- *FREE radical reactions
*CRYSTALS
*X-ray diffraction
*CRYSTALLINITY
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 60
- Issue :
- 57
- Database :
- Academic Search Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 178400891
- Full Text :
- https://doi.org/10.1039/d4cc02454k