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Atomic-molecular perspectives on local high-temperature structure and transport properties of CaCO3-foamed glass.
- Source :
-
Construction & Building Materials . Aug2024, Vol. 439, pN.PAG-N.PAG. 1p. - Publication Year :
- 2024
-
Abstract
- Significant gaps remain in understanding of gas-melt interfaces in foamed glass systems. We attempt to address these gaps by reporting on the transition of local structure, ionic (molecular) diffusion, and melt viscosity of CaCO 3 -foamed soda-lime-silica glass using molecular dynamics calculations and experimental analyses. Our calculations show that despite the continual increase in network modifying CaO, the melt network experiences an abnormal polymerization process in the initial stage because of Na ion penetration from the melt skeleton to the interface. The percolation probability decays from the surface to the center of melt because of the gradual polymerized network structure, boosting nonmonotonic changes in the [SiO 4 ] species, equilibrium constants, and average residual charge per O atom. Furthermore, the diffusion capacities of melt ions and CO 2 molecules peak at 6 wt% CaCO 3 addition, attributed to the combined effects of melt depolymerization and interface constraint. The viscosity jump occurring at 1 wt% CaCO 3 addition results in the optimal sample with an even cellular glass framework and strong matrix. These findings contribute to the precise control of foamed glass with optimal performance. • Gas-melt interfaces in the foamed glass systems are constructed by MD simulations. • Simulations reveal short-range interaction differences between melt basic cations and CO 2 molecules. • An anomalous sub-diffusion regime is attributed to the restriction of gas-liquid interface on diffusion behavior. • A viscosity jump is produced due to the enrichment of network modifiers at the interface. • The viscosity jump boosts the formation of an even cellular glass framework. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 09500618
- Volume :
- 439
- Database :
- Academic Search Index
- Journal :
- Construction & Building Materials
- Publication Type :
- Academic Journal
- Accession number :
- 178478747
- Full Text :
- https://doi.org/10.1016/j.conbuildmat.2024.137347