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Huge enhancement in upconversion luminescence near-infrared emission of KYb (MoO4)2: Er3+ phosphor by doping Y3+ ions.
- Source :
-
Ceramics International . Sep2024:Part A, Vol. 50 Issue 18, p32198-32205. 8p. - Publication Year :
- 2024
-
Abstract
- The KYb(MoO 4) 2 : Er3+, Y3+ phosphors were synthesized by high temperature solid state reaction method. By further doping Y3+ ions, the near-infrared (NIR, 804 nm, 4I 9/2 â 4I 15/2) luminescence of KYb(MoO 4) 2 : 0.1 % Er3+ phosphor is greatly enhanced. Based on the upconversion luminescence (UCL) spectra, the optimal doping concentration of Y3+ ions were 7.5 %. Its near-infrared UCL intensity is about 26.9 times that of undoped Y3+ ions. Through a series of characterization methods, we find that the enhancement of NIR upconversion emission is due to the generation of defect bands. It plays a crucial role in facilitating the transfer of energy from green light level (2H 11/2 , 4S 3/2) to red light level (4F 9/2) and near-infrared level. To explain the luminescence mechanism, the power dependence, UV-VI-NIR absorption spectra, excitation spectra at 804 nm and emission spectra at 380 nm were studied. In addition, the 804 nm single near-infrared UCL intensity of KYb (MoO 4) 2 : Er3+, Y3+ shows a linear variation with temperature in the temperature range of 298 Kâ673 K. The maximum sensitivity is 0.13 % Kâ1. This study provides a new method and theoretical support for the application of near-infrared UCL in optical temperature measurement. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 02728842
- Volume :
- 50
- Issue :
- 18
- Database :
- Academic Search Index
- Journal :
- Ceramics International
- Publication Type :
- Academic Journal
- Accession number :
- 178638470
- Full Text :
- https://doi.org/10.1016/j.ceramint.2024.06.027