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Spin switching and magnetocaloric effect of high-entropy orthoferrite single crystal.
- Source :
-
Ceramics International . Sep2024:Part A, Vol. 50 Issue 18, p32288-32294. 7p. - Publication Year :
- 2024
-
Abstract
- The concept of high-entropy oxides/alloys was introduced into the rare-earth orthoferrite (R FeO 3 , R represents a rare-earth ion) system. Doping five different rare-earth ions with equal molar ratios at the R -site, a single crystal of high-entropy orthoferrite (Y 0.2 Sm 0.2 Eu 0.2 Gd 0.2 Er 0.2)FeO 3 (HERFO) was synthesized using optical floating zone method. At high temperatures, the weak ferromagnetic (wFM) moments induced by the distortion of the Fe sublattices align along the c axis, with a spin configuration of Γ 4. As the temperature decreases, a spin reorientation transition (SRT) occurs from Γ 4 to Γ 2 due to the Fe3+- R 3+ super-exchange interactions, with an immediate state Γ 24. The wFM moments gradually rotate from the c axis to the a axis within the ac plane. In the zero-field-cooling (ZFC) mode, both the type-I and type-II spin switching (SSW) are observable along the a axis. Under low magnetic fields, the type-II SSW is magnetically controlled. The trigger temperature and variation in net moment of the type-II SSW exhibit systematic changes concerning the applied magnetic field. The rich magnetic phase transitions in HERFO make it a promising candidate for spintronic applications aimed at spin manipulation. Additionally, HERFO single crystal exhibits a large magnetocaloric effect (MCE) and magnetic entropy anisotropy, with the negative magnetic entropy change (‐ Δ S m) along the c axis (14.45 J/(kg·K)) being greater than that along the a and b axes (9.57 J/(kg·K) and 10.32 J/(kg·K)). Consequently, HERFO holds great promise as a novel material for magnetic refrigeration applications aimed at achieving rotational magnetic cooling. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 02728842
- Volume :
- 50
- Issue :
- 18
- Database :
- Academic Search Index
- Journal :
- Ceramics International
- Publication Type :
- Academic Journal
- Accession number :
- 178638480
- Full Text :
- https://doi.org/10.1016/j.ceramint.2024.06.036