Mercury isotopes of the Late Ordovician to Middle Triassic tuff layers in South China link the fate of ancient volcanism and the mass extinction.

[Display omitted] • Distinct Δ199Hg values of several tuff layers suggest that their magma sources can be different. • Volcanisms triggered the Late Ordovician and end-Guadalupian mass extinctions. • Hg isotopes as a useful proxy in revealing the type of volcanism in geological history. Mercury (Hg) anomalies in sedimentary records are a newly developed proxy of large volcanism in the geological past. Tuff layers host abundant volcanic ash and record key information on the type of volcanic emission (e.g., arc volcanism and large igneous province eruptions). Here, we measured the Hg isotopic compositions of several tuff layers in South China. Tuff samples in the Late Ordovician Wufeng Formation and the Middle Triassic Guanling Formation mostly show positive Δ199Hg values of – 0.01 to 0.10‰ and – 0.06 to 0.16‰, respectively, suggesting arc volcanism occurred during these two periods. Tuff samples in the Middle Permian Dachang Layer mostly show near-zero Δ199Hg values (– 0.08 to 0.00‰), suggesting volcanism was driven by the Emeishan large igneous province eruption. Results of this study verify Hg isotopes as a useful proxy in revealing the type of volcanism in geological history. [ABSTRACT FROM AUTHOR]