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Pd Immobilization Phenanthroline-2,9-Dicarbaldehyde Modified Magnetic CuBDC MOF as a Reusable Heterogeneous Catalyst for Suzuki-Miyaura Cross-Coupling Reactions.
- Source :
-
Polycyclic Aromatic Compounds . 2024, Vol. 44 Issue 6, p4065-4080. 16p. - Publication Year :
- 2024
-
Abstract
- A porous magnetic multifunctional copper-based metal-organic framework (MOF) was developed through combined covalent and dative post-synthetic modification (PSM) of the CuBDC. In this regard, a novel magnetic metal-organic framework (MMOF) consisting of supported 1,10-phenanthroline-2,9-dicarbaldehyde (Fe3O4@Cu(BDC)-NH2-PHD) has been fabricated by post-synthetic modifications of Fe3O4@Cu(BDC)-NH2. Subsequently, the prepared nanocomposites were modified using palladium chloride ions (Fe3O4@Cu(BDC)-NH2-PdPHD) to impart catalytic sites. As a result, the fabricated magnetic porous catalyst exhibited great catalytic activity in Suzuki-Miyaura cross-coupling reactions. Some of the essential advantages of the synthesized catalyst are; high catalytic activity, short reaction times, mild conditions, high thermal stability, and reusability. Moreover, his porous magnetic nanomaterial can be used as a new support to immobilize other metals in different catalytic reactions. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 10406638
- Volume :
- 44
- Issue :
- 6
- Database :
- Academic Search Index
- Journal :
- Polycyclic Aromatic Compounds
- Publication Type :
- Academic Journal
- Accession number :
- 178651880
- Full Text :
- https://doi.org/10.1080/10406638.2023.2244632