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Pentafluorophenyl Copper–Biarylsulfoxide Complexes: Synthesis and Photoreactivity.
- Source :
-
Molecules . Jul2024, Vol. 29 Issue 14, p3332. 10p. - Publication Year :
- 2024
-
Abstract
- Pentafluorophenyl copper(I)–biarylsulfoxide complexes, existing as [Cu(C6F5)]4L2, both in solution and in the solid state, were prepared and thoroughly characterized. Subsequently, the photochemistry of the complexes was explored, showing inherent photoreactivity of the biarylsulfoxide moiety within the coordination sphere of the copper. Photoinduced cross-coupling reactions between the anthryl moiety of bis-anthracenylsulfoxide and pentafluorobenzene, and synthesis of Cu2O (cuprite), were demonstrated. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 14203049
- Volume :
- 29
- Issue :
- 14
- Database :
- Academic Search Index
- Journal :
- Molecules
- Publication Type :
- Academic Journal
- Accession number :
- 178690338
- Full Text :
- https://doi.org/10.3390/molecules29143332