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Synthesis of Al-enriched beta zeolite nanocrystals by using DABCO di-cationic quaternary ammonium as organic structure directing agent.
- Source :
-
Microporous & Mesoporous Materials . Oct2024, Vol. 378, pN.PAG-N.PAG. 1p. - Publication Year :
- 2024
-
Abstract
- Al-enriched Beta zeolite nanocrystals with densely populated acid sites and enhanced mass transfer efficiency have been demonstrated to show promising catalytic performance. In this work, low Si/Al ratio (8–9) Beta nanocrystals (about 20 nm) was synthesized by using DABCO based di-cationic quaternary ammonium salts as organic structure directing agent with high solid yield (>95 %). The hydrothermal synthesis process was followed by monitoring the intermediate products at different time intervals, through which the key role of the di-cationic quaternary ammonium for the formation of Beta nuclei was identified. The promising catalytic performance of the Al-rich Beta nanocrystals in 1,3,5-triisopropylbenzene transalkylation with benzene was attributed to the high density and enhanced accessibility of acid sites. [Display omitted] • Beta Zeolite with enriched Al content (Si/Al = 8.6) and small crystal size (20 nm) was efficiently synthesized by using DABCO di-quaternary ammonium salt as the SDA. • The key role of the di-cationic quaternary ammonium for the formation of Beta nuclei was identified. • The densely populated acid site, boosted by the enhanced accessibility, improved the intrinsic catalytic activity for transalkylation of 1,3,5-triisopropylbenzene with benzene. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 13871811
- Volume :
- 378
- Database :
- Academic Search Index
- Journal :
- Microporous & Mesoporous Materials
- Publication Type :
- Academic Journal
- Accession number :
- 178732073
- Full Text :
- https://doi.org/10.1016/j.micromeso.2024.113251