Enhancement of Soil Arsenic Mobilization through Hydrochar from Arsenic-Contaminated Boehmeria Nivea: Roles of Alkali-Modification and Soil Microbial Modulation.

The reuse of heavy-metal hyperaccumulator waste has emerged as a critical constraint in the implementation of phytoremediation to control heavy-metal pollution. Ramie (Boehmeria nivea) is a well-established arsenic (As) hyperaccumulator that has been widely used in the remediation of As-contaminated sites in recent years. To facilitate multipurpose development and the recycling of ramie straw contaminated with heavy metals, a study investigated the preparation of hydrochar (HC) at different temperatures and assessed the feasibility of reintroducing the HC into the soil. The results indicated higher yields, increased nutrient contents, and reduced As percentage levels at a hydrothermal carbonization temperature of 240°C. Treatment with a 300 mmol/L sodium hydroxide solution resulted in the removal of As from HC, ranging from 77.06% to 87.60%, effectively facilitating the reuse of HC. The application of alkali-modification HC in As-contaminated soil not only enhances soil properties but also augments the potential population of dominant microorganisms that promote soil arsenic mobilization, thereby improving arsenic mobilization capacity in mining soil. This study offers a viable strategy for enhancing the phytoremediation efficiency of As-contaminated soil and establishing a recycling system for As hyperaccumulator resources in the future. [ABSTRACT FROM AUTHOR]