Interactions between polymer molecules and hydrodynamic responses in multi-ion induced charge electroosmosis.

• Induced charge electroosmosis in complex electrochemical scenarios concomitant with multi-ion and polymer rheology. • Asymmetric flow patterns and altered energy /interfacial-force distributions. • Kinetic energy changes due to diverse viscosity ratios and shear-thinning dependencies. • New flow instability features and spectral decay indices due to the addition of polymer molecules. • The strong coupling of electrokinetic transport and fluid flow phenomena in electrochemical interfaces. Induced charge electroosmosis (ICEO) can assist lab-on-a-chip devices and macromolecular separation involving interface, multi-ion species, and solution properties. To supplement the mechanistic insights into the ICEO phenomenon in complex electrochemical scenarios, we numerically address electrokinetic ion transport–fluid flow coupling regulated by multi-ion species and polymer macromolecular rheology around a polarized cylinder. The physics of the ICEO are analysed from multiple perspectives, including the azimuthal velocity, flow type, energy distribution, interfacial ion transport, and electroelastic instability. The main findings are as follows: (1) Deviations under neutral pH conditions (multi-ion species) cause flow field asymmetry and alter the input energy distribution (PE) in the tight double layer. Polymers greatly modify the interfacial force features in ion-enriched regions, as identified by the first stress difference (N 1). (2) The kinetic energy vs. viscosity ratio (β) represents the nonlinear enhancement curve E k = 0.011 * exp (β / 0.64) - 0.0138 due to the weakened effective viscosity R vis . In addition, shear thinning notably lifts the charge density and salt concentration at the cylinder surface, which boosts the PE. (3) Quadrupolar vortex modes impact the positive correlation between β and the ion current (J total) at different pH levels, resulting in less ion current dependence for small β. A low enhancement efficiency occurs at 10-4 ≤ α (molecular anisotropy) ≤ 0.1, whereas a high efficiency exists at α > 0.1. Electroelastic instabilities are confirmed by the spatiotemporal evolution of the velocity fluctuation, with a broadband structural power-law decline in the power spectral density. These results allow microdevice mixing manipulation and disclose non-Newtonian barrier of electrokinetic dynamics. [ABSTRACT FROM AUTHOR]