Boosting the lattice oxygen reactivity of perovskite electrocatalyst via less Ru substitution.

The successful deployment of efficient oxygen evolution reaction (OER) electrocatalysts is highly essential for multiple clean-energy-related conversion technologies. Perovskite oxides, with compositional diversity and elemental complexity, are a classic kind of OER electrocatalysts, whereas their activity remains insufficient under the traditional adsorbate evolution mechanism (AEM) due to limited scaling relations. Herein, taking the Ba 0.5 Sr 0.5 Co 0.8 Fe 0.2 O 3-δ (BSCF) perovskite as a model system, we find a less Ru substitution strategy to boost the lattice oxygen reactivity for improved OER. The OER behavior of BSCF is greatly ameliorated as Ru doping reaches an optimal level (BSCFR0.1), delivering a lowered overpotential by 45 mV at 10 mA cm−2. Notably, such doping remarkably triggers the generation of more surface oxygen vacancies, promotes internal charge transfer, and enlarges the surface hydrophilicity, hence facilitating more lattice oxygen to participate in the surface reaction. These results demonstrate the feasibility of Ru incorporation for ameliorating the OER behavior of perovskites, and such strategy can be further leveraged to design other remarkable perovskite-based OER catalytic materials. • The Ru-doped BSCF series is synthesized by a simple solid-state reaction approach. • The OER behavior is greatly ameliorated as Ru doping reaches an optimal level. • Ru doping can trigger more oxygen vacancies, increase Co–O covalency, and enlarge the surface hydrophilicity. • Such doping also facilitates more lattice oxygen to participate in the surface reaction. [ABSTRACT FROM AUTHOR]