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Bifunctional nanocomposites formed from magnetic lignin-derived carbon and molybdenum disulfide for efficient pollutant removal.

Authors :
Jia, Jie-Ping
Wang, Guan-Long
Xiao, Ling-Ping
Sun, Shao-Fei
Ren, Zhi-Hong
Xiao, Wei-Dong
Sánchez, Julio
Sun, Run-Cang
Source :
Separation & Purification Technology. Dec2024, Vol. 350, pN.PAG-N.PAG. 1p.
Publication Year :
2024

Abstract

[Display omitted] • Lignin valorization with a novel "waste treatment with waste" concept. • Bifunctional nanocomposites were fabricated with lignin-derived carbon and MoS 2. • Excellent removal capacity of Pb(II) and MB by activating peroxymonosulfate. • The adsorption capacity of Pb(II) by Fe 3 O 4 /PLC-MoS 2 achieved 236.1 mg/g. • Fe 3 O 4 /PLC-MoS 2 degraded MB within 20 min with a degradation rate up to 90.0 %. The development of inexpensive and robust bifunctional nanocomposites toward efficient pollutant removal is crucial for wastewater remediation. Herein, we report a novel strategy for fabrication of magnetic nanocomposites loaded with molybdenum disulfide (Fe 3 O 4 /PLC-MoS 2) using lignin biomacromolecules for efficient pollutant removal. The Fe 3 O 4 /PLC-MoS 2 exhibit excellent pollutant removal capacity: The adsorption capacity of Pb(II) achieve 236.1 mg/g and the methylene blue (MB) degradation rate is up to 90.0 % within 20 min. The adsorption mechanism reveal that the enhanced removal properties is due to that the S atoms on the loaded MoS 2 could convert into soluble sulfide and react with Pb(II) to form white precipitate β-Pb 3 O 2 SO 4. Moreover, the experiments results demonstrate that the Fe 3 O 4 /PLC-MoS 2 has a low bandgap, which can activate PMS to produce reactive oxygen species and degrade MB molecules efficiently. Notably, the Fe 3 O 4 /PLC-MoS 2 demonstrate continued outstanding wastewater remediation capabilities even in scenarios where Pb(II) and MB coexisted. Overall, this study offers a viable and eco-friendly design of dual function removal material by using lignin waste toward promising implications for wastewater treatment. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
13835866
Volume :
350
Database :
Academic Search Index
Journal :
Separation & Purification Technology
Publication Type :
Academic Journal
Accession number :
179496718
Full Text :
https://doi.org/10.1016/j.seppur.2024.128010