Nonradical-dominated peroxymonosulfate activation by perylenetetracarboxylic acid nanosheet photocatalyst for efficient degradation of bisphenol a under visible-light irradiation.

[Display omitted] • The permanent internal electric fields facilitates the separation and migration of photogenerated carriers of PTA. • A transformation of radical–to nonradical-dominated pathway of PMS activation by the photoexcited PTA was confirmed. • The PTA exhibited outstanding photocatalytic activity for bisphenol A removal in presence of PMS under visible light irradiation. As a green, highly efficient, and sustainable technology, photocatalytic peroxymonosulfate (PMS) activation is a promising strategy for wastewater treatment. Moreover, the development of photocatalysts with excellent PMS activation performance is highly desirable for removing refractory organic contaminants from wastewater. Herein, perylenetetracarboxylic acid (PTA) nanosheets obtained using a facile method were explored as a highly efficient photocatalyst with a high PMS activation ability for bisphenol A (BPA) removal. Experimental results indicated that BPA can be removed within 16 min using PTA under optimal conditions. As confirmed through radical quenching, electron paramagnetic resonance spectroscopy, galvanic-oxidation-process experiments, and density functional theory calculations, photoinduced electrons and holes from PTA trigger PMS activation and thereby convert the reaction routes of BPA degradation from radical- to nonradical-dominated. The BPA degradation pathway was also studied using intermediate analysis and Fukui functions. Overall, the findings of this study shed light on organic semiconductor photocatalysts for nonradical-dominated PMS activation with regard to recalcitrant-organic-pollutant removal. [ABSTRACT FROM AUTHOR]