Decoding Methane Flow in Fractured Clay: A Semi‐Analytical Model With Matrix Diffusion and Advection.

ABSTRACT Landfills emissions, ranking as the third‐largest anthropogenic source of methane in the atmosphere, pose environmental challenges and threaten public health. The pivotal role of clay as a mitigating agent for methane emission within landfill cover systems cannot be overstated; however, our understanding of methane escape from fractured clay remains limited. This study aims to address the existing gaps by proposing a robust analytical model of methane transport in both fractures and clay matrix. Our investigation also includes a dimensionless analysis to govern the relative significance of diffusion and advection in methane emission from fractured clay, systematically reviewing factors such as the degree of water saturation (<italic>Sr</italic>) and fracture width. The methane concentration profiles in cracked clay demonstrated escalating sensitivity to Péclet (<italic>Pe</italic>) numbers, especially when advection dominates transport. Our findings also highlight the prevalence of preferential methane flow with increasing <italic>Sr</italic> in the clay matrix. The flux of methane emission from fractures at <italic>Sr</italic> = 0.8 was 130 times greater than that from intact clay. However, the study necessitates considering methane emission from clay matrix, particularly in dry clay conditions (<italic>Sr</italic> = 0.2 and 0.4). The accumulated methane emission flux from intact clay, more than that emitted from fractures by about 2.5 times at <italic>Sr</italic> = 0.2, was 1.3 × 10−5 g/m/s. The findings significantly advance the understanding of gas transport in fractured geomaterials, revealing the effect of water saturation and crack width on methane emissions from fractures. Overall, the outcomes emphasize the inclusion importance of methane emission from cracked clay in the design of gas barriers. [ABSTRACT FROM AUTHOR]