Sensitive Detection and Visual Recognition of Jatrorrhizine Based on a Fluorescent Eu Coordination Polymer Probe.

ABSTRACT Based on 4‐([2,2′:6′,2″‐terpyridin]‐4′‐yl) benzoic acid ligand (Htpba), a fluorescent lanthanide coordination polymer was successfully synthesized, namely, [Eu (tpba)3]n (<bold>1</bold>). The single‐crystal diffraction analysis shows that Eu3+ ions in complex <bold>1</bold> are alternately connected with tpba3− ligands to form a one‐dimensional chain structure, which further constitutes a three‐dimensional supramolecular architecture through the π···π interactions. Complex <bold>1</bold> demonstrated excellent stability of thermogravimetry; and displayed good fluorescence intensity in aqueous solution with a wide pH range. In this work, complex <bold>1</bold> was used as a fluorescence sensor for the detection of jatrorrhizine molecule (JAT). It was found that complex <bold>1</bold> had high sensitivity with the detection limit of 1.02 × 10−8 M, and simultaneously displayed specific selectivity and reutilization for the exploration of JAT molecule. The static quenching, the absorption competition, the electrostatic interactions, and the photo‐induced electron transfer process are responsible for the recognition mechanism of complex <bold>1</bold> with sensing JAT. It is worth mentioning that a fluorescent film based on complex <bold>1</bold> and a light‐emitting diode device coated with the powder of complex <bold>1</bold> were successfully fabricated, which could rapidly recognize JAT molecule with the naked eye further. [ABSTRACT FROM AUTHOR]