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Denitrative Sulfonylation of Nitroarenes with Sodium Sulfinates.

Authors :
Da Luz, Jonathan
Čierna, Michaela
Cooper, Bradley D.
Harris, Thomas D.
Lim, Ethan R. X.
Carney, Jonathan R.
James, Michael J.
Source :
Synthesis. Nov2024, Vol. 56 Issue 21, p3253-3260. 8p.
Publication Year :
2024

Abstract

A one-step method to convert nitroarenes into aryl sulfones under operationally simple, transition-metal-free conditions is described. A range of nitroarenes were reacted with sodium sulfinates and caesium carbonate in N , N ′-dimethylpropyleneurea to afford aryl sulfones in up to 83% yield. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
00397881
Volume :
56
Issue :
21
Database :
Academic Search Index
Journal :
Synthesis
Publication Type :
Academic Journal
Accession number :
180302932
Full Text :
https://doi.org/10.1055/a-2295-8639