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Semiconducting BaS3:La2S3:DyS1.8 multinary metal chalcogenide hetero-system prepared via single source precursor route: expounding energy storage potential.

Authors :
Jaffri, Shaan Bibi
Ahmad, Khuram Shahzad
Al-Hawadi, Jehad S.
Maley, Niharika
Gupta, Ram K.
Ashraf, Ghulam Abbas
Bahajjaj, Aboud Ahmed Awadh
Source :
Applied Physics A: Materials Science & Processing. Nov2024, Vol. 130 Issue 11, p1-12. 12p.
Publication Year :
2024

Abstract

The current study is concerned with understanding the synthesis and application of the diversified BaS3:La2S3:Dy1.8 dithiocarbamate sulphide by the single source precursor (SSP) approach. Analytical approaches were used to evaluate the optical, crystalline, vibrational crosslinking, morphological, and thermal properties of BaS3:La2S3:Dy1.8 chalcogenide. The synthesized chalcogenide has an average crystallite size of 16.35 nm and mixed phases, with a direct band gap energy of 3.9 eV. The study of functional groups revealed the presence of metal sulphide bonds. In terms of morphology, BaS3:La2S3:Dy1.8 chalcogenide has an uneven shape with a small amount of aggregation. The electrochemical charge storage behavior of BaS3:La2S3:Dy1.8 was studied using a nickel foam electrode. The trichalcogenide-decorated electrode exhibited charge-storing behavior, with a specific capacitance of 723 F g− 1 determined by cyclic voltammetry. The electrode has a specific power density of 11,166 W kg− 1 and a low series resistance of 0.9 Ω, as shown by impedance measurements. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
09478396
Volume :
130
Issue :
11
Database :
Academic Search Index
Journal :
Applied Physics A: Materials Science & Processing
Publication Type :
Academic Journal
Accession number :
180934900
Full Text :
https://doi.org/10.1007/s00339-024-07947-0