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通过自由基历程烯烃 1, 2-双官能团化反应同时构建C―O键和 C―X键研究进展.

Authors :
吴丹清
刘佳俊
李天宇
徐大振
苗志伟
Source :
University Chemistry. 2024, Vol. 39 Issue 11, p146-157. 12p.
Publication Year :
2024

Abstract

The 1,2-difunctionalization of olefins via radical pathways is a crucial method in organic synthesis for the direct formation of C―X (X = C, N, O, etc.) bonds from olefins. This approach offers several advantages, including high regioselectivity, step economy, and atom economy, making it compatible with the principles of green chemistry. The development of simple and efficient methods for constructing carbon-oxygen bonds is a significant area of interest in organic chemistry due to the prevalence of organic functional compounds containing these bonds. This review summarizes the recent progress in constructing carbon-oxygen bonds concurrently with carbon-carbon, carbonnitrogen, carbon-sulfur, and carbon-halogen bonds. Additionally, the article discusses the future directions for research in this field. [ABSTRACT FROM AUTHOR]

Details

Language :
Chinese
ISSN :
10008438
Volume :
39
Issue :
11
Database :
Academic Search Index
Journal :
University Chemistry
Publication Type :
Academic Journal
Accession number :
181124461
Full Text :
https://doi.org/10.12461/PKU.DXHX202403087