A ditopic receptor for cation binding and facilitated transport through a supported liquid membrane

Abstract: The binding properties of an artificial receptor towards a series of cations including Li+, Na+, K+, Mg2+, Ca2+, Ba2+, Fe2+ and Al3+ in acetonitrile are described. The receptor comprises a photo-responsive pyrene unit connected via a short spacer to a 2,2′:6′,2″-terpyridine metal ion binding site. Interaction of cations with the receptor was monitored by changes in absorption profile and the association constants calculated for 1:1 and 1:2 cation:ligand binding fall within the range log β =3–12. The receptor is highly fluorescent and quenching of the emission is observed upon cation binding. The potassium picrate transport properties of the membrane-bound receptor are also described. This receptor when immobilised in a polymer support, which separates two aqueous solutions, has been shown to transport potassium ions in the dark with a flux rate of 1.5×108 mol/sm2. In contrast, when the membrane-bound receptor is selectively illuminated with light (λ >400nm), the flux increases to 2.0×108 mol/sm2. The transport efficiency depends on the nature of the trap used in the receiver phase. [Copyright &y& Elsevier]