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Mechanistic investigation on the reaction of 1,1-di-p-substituted phenyl-2,2-dinitroethylene with 1-benzyl-1,4-dihydronicotin-amide in oxygen saturated acetonitrile—clear evidence for intermediate mechanism
- Source :
-
Tetrahedron Letters: International Organ for the Rapid Publication of Preliminary Communications in Organic Chemistry . Aug2005, Vol. 46 Issue 34, p5739-5742. 4p. - Publication Year :
- 2005
-
Abstract
- Abstract: The reaction of 1-benzyl-1,4-dihydronicotinamide with a series of 1,1-di-p-substituted-phenyl-2,2-dinitroethylenes in oxygen-saturated acetonitrile produced various amounts of the corresponding ethanes and diaryl ketones according to the electronic structure of the substituent groups indicating a spectrum of intermediate mechanism between polar mechanism and SET mechanism. [Copyright &y& Elsevier]
- Subjects :
- *ETHANES
*KETONES
*ALKANES
*ORGANIC compounds
Subjects
Details
- Language :
- English
- ISSN :
- 00404039
- Volume :
- 46
- Issue :
- 34
- Database :
- Academic Search Index
- Journal :
- Tetrahedron Letters: International Organ for the Rapid Publication of Preliminary Communications in Organic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 18150943
- Full Text :
- https://doi.org/10.1016/j.tetlet.2005.06.095