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Cyaphide group transfer from covalent metal complexes: contrasting pathways to transmetallation.
- Source :
-
Chemical Communications . 1/14/2025, Vol. 61 Issue 4, p725-727. 3p. - Publication Year :
- 2025
-
Abstract
- We describe two contrasting transmetallation reactions between the gold(I) cyaphide complex, Au(IDipp)(CP) (IDipp = 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene), and low oxidation state main-group and transition-metal complexes. The reactivity observed highlights the pseudo-halide character of the cyaphide ion. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 61
- Issue :
- 4
- Database :
- Academic Search Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 182102650
- Full Text :
- https://doi.org/10.1039/d4cc06131d