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Kinetics of the reaction of beta-methoxy-alpha-nitrostilbene with cyanamide in 50% DMSO-50% water...

Kinetics of the reaction of beta-methoxy-alpha-nitrostilbene with cyanamide in 50% DMSO-50% water...

Authors :
Bernasconi, Claude F.
Leyes, Aquiles E.
Source :
Journal of Organic Chemistry. 04/16/99, Vol. 64 Issue 8, p2897. 6p. 8 Diagrams, 1 Chart, 2 Graphs.
Publication Year :
1999

Abstract

Examines the kinetics of the reaction of beta-methoxy-alpha-nitrostilbene (1-OMe) with cyanamide over a pH range from 8.5 t 12.4. Nucleophilic reactivity of cyanamide; Reactions of 1-OMe with thiolate ions, alkoxide ions and some amines; Combined field effect/pi-acceptor properties of the cyano group; Reactivity of the neutral cyanamide.

Subjects

Subjects :
*STILBENE
*CYANIDES

Details

Language :
English
ISSN :
00223263
Volume :
64
Issue :
8
Database :
Academic Search Index
Journal :
Journal of Organic Chemistry
Publication Type :
Academic Journal
Accession number :
1821036
Full Text :
https://doi.org/10.1021/jo990044u