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Crossover of Ba(Ti,Y)O3 Solid Solutions to Ba3Ti2YO8.5–BaTiO3 Composites and their Dielectric Properties.
- Source :
-
Journal of the American Ceramic Society . Oct2005, Vol. 88 Issue 10, p2775-2779. 5p. - Publication Year :
- 2005
-
Abstract
- Ceramic samples with the nominal composition (1− x) BaTiO3+ x Ba3Ti2YO8.5 ( x=0−0.535) were prepared by the mixed oxide method. X-ray diffraction (XRD) analysis shows that the materials are of single phase with a cubic symmetry as x≤0.16. The compositions of the solid solutions ( x≤0.16) can be expressed equivalently as Ba(Ti1− yY y)O3−δ ( y≤0.122, y= x/(1+2 x)). For x>0.16, the materials are diphasic composites consisting of Ba(Ti1− yY y)O3 ( y=0.122) and Ba3Ti2YO8.5. The microstructure observation by scanning electron microscopy supports the XRD result. The dielectric behavior and phase transitions of the solid solutions ( x≤0.16) vary with different Y concentrations. The dielectric constant of the composites ( x>0.16) follows approximately the Lichteneker relation in a wide temperature range. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00027820
- Volume :
- 88
- Issue :
- 10
- Database :
- Academic Search Index
- Journal :
- Journal of the American Ceramic Society
- Publication Type :
- Academic Journal
- Accession number :
- 18221040
- Full Text :
- https://doi.org/10.1111/j.1551-2916.2005.00501.x