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Coordination chemistry of Re complexes with 2(2′-pyridyl)benzimidazole
- Source :
-
Inorganica Chimica Acta . Sep2005, Vol. 358 Issue 13, p3914-3918. 5p. - Publication Year :
- 2005
-
Abstract
- Abstract: Two new Re(III) and Re(IV) complexes with 2(2′-pyridyl)benzimidazole (pbimz) were prepared and their crystal and molecular structures established by single-crystal X-ray diffraction. Reaction of [ReOCl2(OEt)(PPh3)2] with the ligand gave red cis(Cl),trans(P)-[ReCl2(PPh3)2(pbimz)]Cl (1), while red [ReCl4(pbimz)]·OPPh3 (2) was obtained from [ReCl3(PhC(O)C(O)Ph)(PPh3)] and pbimz in the presence of perchlorate. The compounds were characterized by elemental analysis, FAB-MS, UV–Vis, IR, NMR spectroscopy and magnetic susceptibility measurements. [Copyright &y& Elsevier]
- Subjects :
- *SPECTRUM analysis
*MAGNETIC susceptibility
*BENZIMIDAZOLES
*ALBENDAZOLE
Subjects
Details
- Language :
- English
- ISSN :
- 00201693
- Volume :
- 358
- Issue :
- 13
- Database :
- Academic Search Index
- Journal :
- Inorganica Chimica Acta
- Publication Type :
- Academic Journal
- Accession number :
- 18300538
- Full Text :
- https://doi.org/10.1016/j.ica.2005.06.019