Liquid-phase oxidation of benzene to phenol by molecular oxygen over transition metal substituted polyoxometalate compounds

Abstract: Transition metal substituted polyoxometalate (TMSP) compounds were used as catalysts for the liquid-phase oxidation of benzene to phenol by molecular oxygen with ascorbic acid as a reducing agent in an acetone/sulfolane/water mixed solvent. [(C4H9)4N]5[PW11CuO39(H2O)] is the best catalyst tested in this study. It showed 9.2% benzene conversion (TON=25.8) and 91.8% selectivity to phenol for the oxidation of benzene at 323K for 12h. The effect of the substituted transition metal in the TMSP compounds on the benzene conversion is in the order: Cu>V>Fe≫Mn>Ti>Cr>Co>Ni>Zn. The effect of the central atom in the TMSP compounds on the benzene conversion is in the order: P≈Si>Ge>B. [SiW11O39]8− is a good polyoxometalate ligand for transition metal ions as [PW11O39]7− for the oxidation of benzene. The selectivity to phenol was dramatically improved by adding the sulfolane solvent, but the benzene conversion decreased when a large amount of sulfolane was used in the mixed solvent. Ascorbic acid is indispensable for forming phenol from benzene oxidation by O2 over TMSP compounds. Higher O2 pressure in the catalytic system ensured more oxygen molecules solving in the solvent, and promoted the benzene conversion. [Copyright &y& Elsevier]