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Cuprophilicity-Induced Cocrystallization of [Cu2(4,4'-bpy)(CN)2]n Sheets and [Cu(SCN)]n Chains into a 3-D Pseudopolyrotaxane.
- Source :
-
Inorganic Chemistry . 10/17/2005, Vol. 44 Issue 21, p7301-7303. 3p. 3 Diagrams. - Publication Year :
- 2005
-
Abstract
- The cocrystallization of [Cu(SCN)]n chains and [Cu2(4,4′-bpy)CN)2]n (4,4′-bpy = 4,4′-bipyridine) layers generated a 3-D pseudopolyrotaxane compound, [Cu2(4,4′-bpy)(CN)2].[Cu(SON)] (1), which can also be viewed as a 3-D network constructed by linkages of 2-D sheets and I-D chains via unsupported CuI-CuI interactions. The CuI-CuI contact of 2.651(4) Å in 1 is the shortest unsupported CuI-CuI distance documented to date, indicating cuprophilic attractions. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00201669
- Volume :
- 44
- Issue :
- 21
- Database :
- Academic Search Index
- Journal :
- Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 18673287
- Full Text :
- https://doi.org/10.1021/ic051104j