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Novel pyrazolate-bridged dinuclear Pd(II) diimine complexes that bind inorganic anions
- Source :
-
Inorganic Chemistry Communications . Jul2005, Vol. 8 Issue 7, p656-660. 5p. - Publication Year :
- 2005
-
Abstract
- Abstract: Two pyrazolate-bridged dinuclear Pd(II) diimine complexes {[(phen)Pd]2L2}(NO3)2 (1) and {[(bpy)Pd]2L2}(NO3)2 (2) have been synthesized through metal–metal interaction and spontaneous deprotonation from 1H-3,5-diphenylpyrazole (HL) in aqueous solution. These complexes show Pd(II)⋯Pd(II) interactions and anion binding have been characterized by elemental analyses, 1H and 13C NMR, ESI-MS, UV–Vis and luminescent spectroscopy, and single crystal X-ray diffraction methods. [Copyright &y& Elsevier]
- Subjects :
- *ORGANONITROGEN compounds
*IMINES
*COMPLEX compounds
*ANIONS
Subjects
Details
- Language :
- English
- ISSN :
- 13877003
- Volume :
- 8
- Issue :
- 7
- Database :
- Academic Search Index
- Journal :
- Inorganic Chemistry Communications
- Publication Type :
- Academic Journal
- Accession number :
- 18738824
- Full Text :
- https://doi.org/10.1016/j.inoche.2005.04.011