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Di­aqua­bis­(di­methyl sulfoxide)­bis(2,4-di­nitro­benzoato)­cobalt(II).

Authors :
Miminoshvili, Elguja B.
Miminoshvili, Ketevan E.
Sobolev, Alexandre N.
Source :
Acta Crystallographica: Section E. Apr2005, Vol. 61 Issue 4, pm775-m777. 3p. 2 Color Photographs, 2 Diagrams, 2 Charts.
Publication Year :
2005

Abstract

The title compound, [Co(C7H3N2O6)2(C2H6OS)2(H2O)2], has been prepared and its structure established by an X-ray structure determination in order to assist the modelling of processes of chemisorption of organic salts formed by di­nitro­benzoic acids (DNBH) and secondary amines ( R2NH) by metal surfaces. The 2,4-DNB ions and di­methyl sulfoxide (DMSO) mol­ecules behave as monodentate ligands coord­inated to the Co atom through their O atoms. These ligands, together with two mol­ecules of water, form a slightly distorted octahedral coordination environment for the Co atom which is disposed at a centre of symmetry. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
16005368
Volume :
61
Issue :
4
Database :
Academic Search Index
Journal :
Acta Crystallographica: Section E
Publication Type :
Academic Journal
Accession number :
18817824
Full Text :
https://doi.org/10.1107/S1600536805009050