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Cd1.17Zn0.83B2O5, a new cadmium zinc diborate.
- Source :
-
Acta Crystallographica: Section E . Sep2005, Vol. 61 Issue 9, pi196-i198. 3p. 2 Diagrams, 1 Chart. - Publication Year :
- 2005
-
Abstract
- Crystals of cadmium zinc diborate, Cd1.17Zn0.83B2O5, have been obtained by spontaneous nucleation in a platinum crucible at 1072 K. The crystal structure exhibits diborate groups, B2O54−, sharing O atoms with considerably distorted M1O6 octa­hedra and M2O4 tetra­hedra. Both metal centers are disordered in the proportion Cd:Zn = 0.92:0.08 on the M1 site and Cd:Zn = 0.25:0.75 on the M2 site. A strong second-harmonic generation has been observed for the title compound when excited with an Nd:YAG laser (λ = 1064 nm). [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 16005368
- Volume :
- 61
- Issue :
- 9
- Database :
- Academic Search Index
- Journal :
- Acta Crystallographica: Section E
- Publication Type :
- Academic Journal
- Accession number :
- 18819017
- Full Text :
- https://doi.org/10.1107/S1600536805024608