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Magnesium-mediated carbon-carbon bond formation in aqueous media: Barbier-Grignard allylation...
- Source :
-
Journal of Organic Chemistry . 04/30/99, Vol. 64 Issue 9, p3230. 7p. 8 Diagrams, 3 Charts. - Publication Year :
- 1999
-
Abstract
- Examines the magnesium-mediated Barbier-Grignard type alkylation of aldehydes with alkyl halides in aqueous media. Reaction of aromatic aldehydes with allyl halides; Magnesium-mediated allylation of aldehydes with allyl bromide and iodide; Formation of the pinacol coupling products; Factor affecting the pinacol reaction.
- Subjects :
- *BARBIER reactions
*ALLYL halides
ALDEHYDE reactivity
AROMATIC compound reactivity
Subjects
Details
- Language :
- English
- ISSN :
- 00223263
- Volume :
- 64
- Issue :
- 9
- Database :
- Academic Search Index
- Journal :
- Journal of Organic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 1889631
- Full Text :
- https://doi.org/10.1021/jo982497p