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Side chain-directed complementary cis-coordination of two pyridines on Pd(II): Selective multicomponent assembly of square-, rectangular-, and trigonal prism-shaped molecules
- Source :
-
Journal of Organometallic Chemistry . Nov2005, Vol. 690 Issue 23, p5383-5388. 6p. - Publication Year :
- 2005
-
Abstract
- Abstract: This paper describes a new strategy to regulate multicomponent assembly from two kinds of pyridine-based ligands and cis-protected Pd(II) ions. The introduction of sterically hindered substituents to only one of the two ligands directs the complementary cis-coordination of the two lingads on the Pd(II) center, leading to the selective multicomponent assembly of two- and three-dimensional polynuclear Pd(II) complexes (e.g., square-, rectangular-, and trigonal prism-shaped molecules). [Copyright &y& Elsevier]
- Subjects :
- *INTERMEDIATES (Chemistry)
*ORGANIC compounds
*IONS
*LINE geometry
Subjects
Details
- Language :
- English
- ISSN :
- 0022328X
- Volume :
- 690
- Issue :
- 23
- Database :
- Academic Search Index
- Journal :
- Journal of Organometallic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 18984689
- Full Text :
- https://doi.org/10.1016/j.jorganchem.2005.06.022