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A novel two-dimensional framework solid composed of nanosized molybdenum-oxide molecules: synthesis and characterization of [{Gd(H2O)5}4{Mo36(NO)4O108(H2O)16}]·34 H2O
- Source :
-
Comptes Rendus Chimie . Nov2005, Vol. 8 Issue 11/12, p1922-1926. 5p. - Publication Year :
- 2005
-
Abstract
- Abstract: Reaction of the ammonium salt of keplerate, [{(MoVI)MoVI 5O21(H2O)6}12{MoV 2O4CH3COO)}30]42– with Gd(NO3)3 leads to complex transformations with [{Gd(H2O)5}4{Mo36(NO)4O108(H2O)16}]·34 H2O (1) as final product. According to X-ray structural data it contains anions [Mo36(NO)4O108(H2O)16]12–, cross-linked into a neutral 2D-framework by Gd3+ ions. To cite this article: N.V. Izarova et al., C. R. Chimie 8 (2005) . [Copyright &y& Elsevier]
Details
- Language :
- English
- ISSN :
- 16310748
- Volume :
- 8
- Issue :
- 11/12
- Database :
- Academic Search Index
- Journal :
- Comptes Rendus Chimie
- Publication Type :
- Academic Journal
- Accession number :
- 19008437
- Full Text :
- https://doi.org/10.1016/j.crci.2005.02.025