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Thermodynamic and spectroscopic studies of copper (II) complexes with three bis(amide) ligands derived from l-tartaric acid
- Source :
-
Journal of Inorganic Biochemistry . Dec2005, Vol. 99 Issue 12, p2423-2435. 13p. - Publication Year :
- 2005
-
Abstract
- Abstract: The interactions of three bis(amide) ligands derived from tartaric acid with copper (II) were investigated in aqueous solution by a combination of potentiometry, UV–vis spectrophotometry, electron paramagnetic resonance (EPR), and mass spectrometry. The formation constants of the complexes were measured and their relative structures were reported. The sites of complexation of these ligands are investigated based mostly on their electronic and EPR spectra and on the comparison with the behaviour of some analog compounds. [Copyright &y& Elsevier]
- Subjects :
- *COPPER
*TARTARIC acid
*POTENTIOMETRY
*ELECTRON paramagnetic resonance
*SPECTROMETRY
Subjects
Details
- Language :
- English
- ISSN :
- 01620134
- Volume :
- 99
- Issue :
- 12
- Database :
- Academic Search Index
- Journal :
- Journal of Inorganic Biochemistry
- Publication Type :
- Academic Journal
- Accession number :
- 19126123
- Full Text :
- https://doi.org/10.1016/j.jinorgbio.2005.09.010