Hydrothermal syntheses and structures of a novel zincophosphite, [C6N2H18]·[Zn3(HPO3)4]

Abstract: A novel three-dimensional organically templated zincophosphite, [C6N2H18]·[Zn3(HPO3)4], was synthesized under milder hydrothermal conditions and structurally characterized by single-crystal X-ray diffraction, differential thermal-thermogravimetric analysis, powder X-ray diffraction, 31P MAS NMR spectrum, and IR spectroscopy. It crystallizes in the monoclinic system, space group C2/c with cell parameters: a =8.7820(4)Å, b =14.9417(7)Å, c =15.4943(5)Å, β =92.940(2)°, and Z =4. The structure consists of a network of strictly alternating ZnO4 tetrahedra and pseudo-pyramid, forming 4-membered ring chains. The structure has a 4.8.16-net and 8- and 16-membered ring channels where completely protonated N,N,N′,N′-tetramethylenediamine cations are encapsulated. The structure is stabilized by template-to-framework hydrogen bonding. In phosphites system, this compound possesses extra-large-pores. [Copyright &y& Elsevier]