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Crystal structures of amarine and isoamarine and copper(I) coordination chemistry with their allylation products
- Source :
-
Journal of Organometallic Chemistry . Feb2006, Vol. 691 Issue 5, p1065-1074. 10p. - Publication Year :
- 2006
-
Abstract
- Abstract: The crystal structures of amarine (1) and isoamarine (2), important intermediates in the preparation of 1,2-diphenyl-diaminoethane, were successfully determined. Their allylation products, 1,3-diallyl amarine (1)(CH2 ph name="dbnd" />CH2)2Br (3) and isoamarine bromide (2)(CH2 ph name="dbnd" />CH2)2Br (4) [the crystal structures of (1)(CH2 ph name="dbnd" />CH2)2PF6(3-Br+PF6) and (2)(CH2 ph name="dbnd" />CH2)2PF6 (4-Br+PF6) are also successfully determined to confirm allylation products], react with CuBr to afford (1)2(CH2 ph name="dbnd" />CH2)4(Cu2Br4) (5) and (2)(CH2 ph name="dbnd" />CH2)2(Cu2Br3) (6), respectively. Crystal structures of 5 and 6 reveal that 5 is an anion discrete complex without olefin moiety coordination, and 6 has a 1D infinite chain with olefin moiety coordination as a bridging spacer. The fluorescent emission spectra of 5 (λ emax =570nm) and 6 (λ emax =642nm) were measured, and display a significant difference that can be used for solid state fluorescent sensing them. [Copyright &y& Elsevier]
- Subjects :
- *COPPER
*ETHANES
*SPECTRUM analysis
*BROMIDES
Subjects
Details
- Language :
- English
- ISSN :
- 0022328X
- Volume :
- 691
- Issue :
- 5
- Database :
- Academic Search Index
- Journal :
- Journal of Organometallic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 19620931
- Full Text :
- https://doi.org/10.1016/j.jorganchem.2005.10.040