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Poly[[hexa­aqua­bis(μ3-pyridine-2,5-dicarboxyl­ato-κ4 O: O′, N: O′′)bis­(μ2-pyridine-2,5-dicarboxyl­ato-κ3 O: O′, N)dieuropium(III)copper(II)] dihydrate]

Authors :
Bao-Feng Zhang
Cheng-Zhi Xie
Guang-Qiu Shen
De-Zhong Shen
Xiao-Qing Wang
Source :
Acta Crystallographica: Section E. Feb2006, Vol. 62 Issue 2, pm297-m299. 1p. 2 Diagrams, 2 Charts.
Publication Year :
2006

Abstract

The title polymeric compound, {[Eu2Cu(C7H3O4)4(H2O)6]·2H2O} n, was prepared by a hydro­thermal reaction at 453 K. The EuIII ion has a double-capped trigonal prismatic coordination geometry with an NdNO7 core, while the CuII ion is located on an inversion center and assumes a square-planar coordination geometry. The pyridine-2,5-dicarboxyl­ate dianions bridge the EuIII and CuII ions, forming a three-dimensional polymeric structure. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
16005368
Volume :
62
Issue :
2
Database :
Academic Search Index
Journal :
Acta Crystallographica: Section E
Publication Type :
Academic Journal
Accession number :
19642297
Full Text :
https://doi.org/10.1107/S1600536806000948