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Thermal behavior of 1,3,3-trinitroazetidine.
- Source :
-
Journal of Analytical & Applied Pyrolysis . Jun2006, Vol. 76 Issue 1/2, p1-5. 5p. - Publication Year :
- 2006
-
Abstract
- The thermal behavior of 1,3,3-trinitroazetidine (TNAZ) is studied by means of high-pressure DSC (PDSC), the combination technique of in situ thermolysis cell with rapid-scan fourier transform infrared spectroscopy (thermolysis/RSFT-IR) and fast thermolysis probe with rapid-scan fourier transform infrared spectroscopy (fast thermolysis/RSFT-IR). The thermal decomposition mechanism is proposed. The results show that the decomposition temperature of TNAZ at 1MPa is 264.7 °C, both the C—NO2 and N—NO2 bonds and all the other C—N, C—C and C—H bonds of the four-membered ring of TNAZ are simultaneously broken with an increase in temperature and the gas products detected of thermal decomposition of TNAZ consist of CO2, NO2, N2O and NO. [Copyright &y& Elsevier]
Details
- Language :
- English
- ISSN :
- 01652370
- Volume :
- 76
- Issue :
- 1/2
- Database :
- Academic Search Index
- Journal :
- Journal of Analytical & Applied Pyrolysis
- Publication Type :
- Academic Journal
- Accession number :
- 19768640
- Full Text :
- https://doi.org/10.1016/j.jaap.2005.04.008