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Three halogeno(cyano)cuprates with 1-D helical chains and their efficient luminescence
- Source :
-
Inorganica Chimica Acta . Mar2006, Vol. 359 Issue 5, p1643-1649. 7p. - Publication Year :
- 2006
-
Abstract
- Abstract: Spontaneous resolution in solvothermal reactions through tuning the volume of the templating and space-filling agents (quaternary ammonium cations) lead to three novel halogeno(cyano)cuprates [R4N][Cu(CN)X] (R=Et, X=Cl, 1; R=Et, X=Br, 2; R=Bu, X=I, 3), which all consist of 1-D helical chains. Compounds 1 and 2 reveal to be mesomeric structures while compound 3 exhibits a nonracemic enantiopure topology. Luminescent studies indicate that all three compounds are potential materials for efficient luminescent materials. [Copyright &y& Elsevier]
- Subjects :
- *LIGHT sources
*CATIONS
*AMMONIUM
*LUMINESCENCE
Subjects
Details
- Language :
- English
- ISSN :
- 00201693
- Volume :
- 359
- Issue :
- 5
- Database :
- Academic Search Index
- Journal :
- Inorganica Chimica Acta
- Publication Type :
- Academic Journal
- Accession number :
- 20013514
- Full Text :
- https://doi.org/10.1016/j.ica.2005.12.038