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Tetraaza-copper(II) complex ions suspended in the cyanoargentate networks: X-ray structure and properties of a self-assembled [Cu(3,2,3-tet)] [Ag2(CN)4] having extraordinarily short Ag–Ag distance
- Source :
-
Inorganic Chemistry Communications . May2006, Vol. 9 Issue 5, p533-536. 4p. - Publication Year :
- 2006
-
Abstract
- Abstract: A three-dimensional supramolecule of [Cu(3,2,3-tet)] n {[Ag2(CN)4]} n (1), (3,2,3-tet = N,N′-bis(3-aminopropyl)ethylenediamine), in which [Cu(3,2,3-tet)]2+ cations are suspended in the two-dimensional anionic networks composed of [Ag2(CN)4]2+ building blocks, was synthesized and characterized by X-ray crystallography. Every silver(I) ion is five-coordinated including the silver–silver interaction in anionic network. Variable temperature magnetic susceptibility data indicate weak antiferromagnetic interaction (−0.378cm−1) between copper(II) ions in 1. [Copyright &y& Elsevier]
- Subjects :
- *COMPLEX ions
*X-ray crystallography
*ANTIFERROMAGNETISM
*MAGNETIC susceptibility
Subjects
Details
- Language :
- English
- ISSN :
- 13877003
- Volume :
- 9
- Issue :
- 5
- Database :
- Academic Search Index
- Journal :
- Inorganic Chemistry Communications
- Publication Type :
- Academic Journal
- Accession number :
- 20646829
- Full Text :
- https://doi.org/10.1016/j.inoche.2006.02.026