Back to Search
Start Over
Bis(1-methyl-1 H-tetrazol-5-yl)diazene and two its copper(I) chloride complexes poly[[[μ-1,2-bis(1-methyl-1 H-tetrazol-5-yl)diazene-κ4 N′, N4: N, N4′]dicopper(I)]-di-μ-chloro] and catena-poly[[chlorocopper(I)]-μ-1,2-bis(1-methyl-1 H-tetrazol-5-yl)diazene-κ4 N′, N4: N, N4′]
- Source :
-
Acta Crystallographica: Section C (Wiley-Blackwell) . Jun2006, Vol. 62 Issue 6, pm223-m226. 1p. 6 Diagrams, 3 Charts. - Publication Year :
- 2006
-
Abstract
- While bis(1-methyl-1 H-tetra­zol-5-yl)diazene, C4H6N10, (I), has no crystallographically imposed symmetry, in the two title chloro­copper(I) complexes, [Cu2Cl2(C4H6N10)] n, (II), and [CuCl(C4H6N10)] n, (III), the organic ligands lie across centres of inversion; in (III), the Cu and Cl atoms additionally lie about a twofold rotation axis in the space group P2/ c. Complex (II) forms a two-dimensional coordination polymer containing tetra­hedrally coordinated CuI atoms, and complex (III) forms a one-dimensional coordination polymer containing five-coordinate square-pyramidal CuI atoms. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 01082701
- Volume :
- 62
- Issue :
- 6
- Database :
- Academic Search Index
- Journal :
- Acta Crystallographica: Section C (Wiley-Blackwell)
- Publication Type :
- Academic Journal
- Accession number :
- 21124520
- Full Text :
- https://doi.org/10.1107/S0108270106013199