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Poly[[[(2,2′-bipyridine-κ2 N, N′)cobalt(II)]-μ3-5-hydroxyisophthalato-κ4 O, O′: O′′: O′′′] dihydrate].
- Source :
-
Acta Crystallographica: Section E . Jul2006, Vol. 62 Issue 7, pm1722-m1724. 1p. 5 Diagrams, 2 Charts. - Publication Year :
- 2006
-
Abstract
- In the title compound, {[Co(C8H4O5)(C10H8N2)]·2H2O]} n or {[Co(OH-BDC)(2,2′-bipy)]·2H2O]} n (where OH-H2BDC is 5-hydroxy­isophthalic acid and 2,2′-bipy is 2,2′-bipyridine), the Co atoms are chelated by two N atoms from the 2,2′-bipy ligand and by four O atoms from OH-BDC ligands in a highly distorted octa­hedral geometry. OH-BDC acts as a tetra­dentate ligand, with one carboxyl­ate group chelating one Co atom and the other binding in a monodentate fashion to two other Co atoms to form a one-dimensional zigzag chain. In the crystal structure, one of the solvent water mol­ecules lies on a crystallographic twofold axis. The one-dimensional mol­ecular chains are assembled into a two-dimensional network via O—H⋯O hydrogen-bonding inter­actions, while π–π stacking inter­actions generate a three-dimensional open framework between the two-dimensional networks. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 16005368
- Volume :
- 62
- Issue :
- 7
- Database :
- Academic Search Index
- Journal :
- Acta Crystallographica: Section E
- Publication Type :
- Academic Journal
- Accession number :
- 21509162
- Full Text :
- https://doi.org/10.1107/S1600536806023907