Back to Search Start Over

Photoluminescence of PtII(cyclooctatetraene)(CN)2 originating from a MLCT triplet

Authors :
Kunkely, Horst
Vogler, Arnd
Source :
Inorganic Chemistry Communications. Aug2006, Vol. 9 Issue 8, p827-829. 3p.
Publication Year :
2006

Abstract

Abstract: The complex PtII(cyclooctatetraene)(CN)2 shows a longest-wavelength absorption (λ max =430nm) which is assigned to a (PtII →π∗ C8H8) MLCT transition. At r.t. the solid complex displays an intense orange emission at 572nm which originates from the MLCT triplet. The emission spectrum exhibits a vibrational structure which may indicate an IL contribution. [Copyright &y& Elsevier]

Details

Language :
English
ISSN :
13877003
Volume :
9
Issue :
8
Database :
Academic Search Index
Journal :
Inorganic Chemistry Communications
Publication Type :
Academic Journal
Accession number :
21694953
Full Text :
https://doi.org/10.1016/j.inoche.2006.03.032