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Di-μ-dioxo-bis­({1-[phen­yl(2-pyridyl-κ N)methyl­ene]-2-(pyrrolidin-1-ylthio­carbonyl-κ S)hydrazinato-κ N1}oxovanadium(V)).

Authors :
John, Rohith P.
Sreekanth, A.
Hoong-Kun Fun
Kurup, M. R. Prathapachandra
Chantrapromma, Suchada
Source :
Acta Crystallographica: Section E. Aug2006, Vol. 62 Issue 8, pm1919-m1921. 1p. 3 Diagrams, 2 Charts.
Publication Year :
2006

Abstract

In the title centrosymmetric binuclear complex, [V2(C17H17N4S)2O4], pairs of V atoms are linked by two oxo bridges. The coordination geometry at each VV atom is distorted octa­hedral, involving a pyridine N atom, a thiol­ate S atom, an azomethine N atom from the 1-[phen­yl(2-pyrid­yl)methyl­ene]-2-(pyrrolidin-1-ylthio­carbon­yl)hydrazine(−) ligand, and one terminal O and 2 bridging O atoms. The crystal structure is stabilized by weak inter­molecular C—H⋯O inter­actions. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
16005368
Volume :
62
Issue :
8
Database :
Academic Search Index
Journal :
Acta Crystallographica: Section E
Publication Type :
Academic Journal
Accession number :
21936620
Full Text :
https://doi.org/10.1107/S1600536806026894