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Di-μ-dioxo-bis({1-[phenyl(2-pyridyl-κ N)methylene]-2-(pyrrolidin-1-ylthiocarbonyl-κ S)hydrazinato-κ N1}oxovanadium(V)).
- Source :
-
Acta Crystallographica: Section E . Aug2006, Vol. 62 Issue 8, pm1919-m1921. 1p. 3 Diagrams, 2 Charts. - Publication Year :
- 2006
-
Abstract
- In the title centrosymmetric binuclear complex, [V2(C17H17N4S)2O4], pairs of V atoms are linked by two oxo bridges. The coordination geometry at each VV atom is distorted octa­hedral, involving a pyridine N atom, a thiol­ate S atom, an azomethine N atom from the 1-[phen­yl(2-pyrid­yl)methyl­ene]-2-(pyrrolidin-1-ylthio­carbon­yl)hydrazine(−) ligand, and one terminal O and 2 bridging O atoms. The crystal structure is stabilized by weak inter­molecular C—H⋯O inter­actions. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 16005368
- Volume :
- 62
- Issue :
- 8
- Database :
- Academic Search Index
- Journal :
- Acta Crystallographica: Section E
- Publication Type :
- Academic Journal
- Accession number :
- 21936620
- Full Text :
- https://doi.org/10.1107/S1600536806026894