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Highly Stereoselective Oxidative Esterification of Aldehydes with β-Dicarbonyl Compounds.

Authors :
Woo-Jin Yoo
Chao-Jun Li
Source :
Journal of Organic Chemistry. 8/4/2006, Vol. 71 Issue 16, p6266-6268. 3p. 1 Diagram, 2 Charts.
Publication Year :
2006

Abstract

Copper-catalyzed oxidative esterification of aldehydes with β-dicarbonyl compounds was developed using tert-butyl hydroperoxide as an oxidant. In general, the enol esters were synthesized in good yields (up to 87%) and high stereoselectivity under the optimized reaction conditions. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
00223263
Volume :
71
Issue :
16
Database :
Academic Search Index
Journal :
Journal of Organic Chemistry
Publication Type :
Academic Journal
Accession number :
21955637
Full Text :
https://doi.org/10.1021/jo0606103