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(5,16-Dimethyl-2,6,13,17-tetraazatricyclo[14,4,01,18,07,12]docosane-κ4 N)dinitratocopper(II) trihydrate.
- Source :
-
Acta Crystallographica: Section E . Sep2006, Vol. 62 Issue 9, pm2383-m2385. 3p. 2 Diagrams, 2 Charts. - Publication Year :
- 2006
-
Abstract
- In the title compound, [Cu(NO3)2(C20H40N4)]·3H2O, the Cu atom lies on a crystallographic inversion centre and has a distorted octahedral geometry, with four N atoms of the macrocyclic ligand in the equatorial positions and two O atoms of the axial nitrate ligands. The long axial Cu—O bond of 2.746 (2) Å may result from the Jahn-Teller effect. The macrocyclic ligand adopts the most stable trans-III configuration with the two six-membered rings in chair form and two five-membered rings in a gauche form. [ABSTRACT FROM AUTHOR]
- Subjects :
- *ETHANES
*HYDRATES
*COPPER
*ATOMS
*LIGANDS (Chemistry)
*CROWN ethers
Subjects
Details
- Language :
- English
- ISSN :
- 16005368
- Volume :
- 62
- Issue :
- 9
- Database :
- Academic Search Index
- Journal :
- Acta Crystallographica: Section E
- Publication Type :
- Academic Journal
- Accession number :
- 22243476
- Full Text :
- https://doi.org/10.1107/S1600536806034234