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catena-Poly[[aqua­(2,2′-bipyridine-κ2 N, N′)cadmium(II)]-μ-4-carboxyl­atophenoxy­acetato-κ3 O: O4, O4′].

Authors :
Yang, Yan
Zeng, Ming-Hua
Meng, Fa-Yan
Liang, Hong
Source :
Acta Crystallographica: Section C (Wiley-Blackwell). Sep2006, Vol. 62 Issue 9, pm392-m394. 1p. 5 Diagrams, 2 Charts.
Publication Year :
2006

Abstract

In the title compound, [Cd(C9H6O5)(C10H8N2)(H2O)] n, the CdII atom is coordinated in a distorted octa­hedral fashion by two carboxyl­ate groups (one in a monodentate and one in a bidentate fashion) from two 4-carboxyl­ato­phenoxy­acetate anions, two N atoms from a 2,2′-bipyridine ligand and one aqua ligand. The structure is a helix with a long pitch of 16.441 (5) Å. A three-dimensional supra­molecular network is further constructed through π–π stacking and hydrogen-bonding inter­actions between the helices. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
01082701
Volume :
62
Issue :
9
Database :
Academic Search Index
Journal :
Acta Crystallographica: Section C (Wiley-Blackwell)
Publication Type :
Academic Journal
Accession number :
22390420
Full Text :
https://doi.org/10.1107/S0108270106026783